Bruno Pontecorvo, knowing him and indebtedness to him

Pontecorvo, in 1947, in a Physical Review Letter, pointed out that given the results of the experiment of Conversi, Panciini and Piccioni, the Fermi interaction may very well be universal, but this was too imaginative at the time and universally rejected. I owe to Pontecorvo the suggestion to do the experiment for which I shared a Nobel prize

Assessing the critical material constraints on low carbon infrastructure transitions

We present an assessment method to analyze whether the disruption in supply of a group of materials endangers the transition to low-carbon infrastructure. We define criticality as the combination of the potential for supply disruption and the exposure of the system of interest to that disruption. Low-carbon energy depends on multiple technologies comprised of a multitude of materials of varying criticality. Our methodology allows us to assess the simultaneous potential for supply disruption of a range of materials. Generating a specific target level of low-carbon energy implies a dynamic roll-out of technology at a specific scale. Our approach is correspondingly dynamic, and monitors the change in criticality during the transition towards a low-carbon energy goal. It is thus not limited to the quantification of criticality of a particular material at a particular point in time. We apply our method to criticality in the proposed UK energy transition as a demonstration, with a focus on neodymium use in electric vehicles. Although we anticipate that the supply disruption of neodymium will decrease, our results show the criticality of low carbon energy generation increases, as a result of increasing exposure to neodymium-reliant technologies. We present a number of potential responses to reduce the criticality through a reduction in supply disruption potential of the exposure of the UK to that disruption

Spatial patterns in the evolution of Cenozoic dynamic topography and its influence on the Antarctic continent

Our knowledge of dynamic topography in Antarctica remains in an infancy stage compared to other continents. We assess the space-time variability in dynamic topography in Antarctica by analysing grids of global dynamic topography in the Cenozoic (and late Cretaceous) based on the tomographic model S40RTS. Our model reveals that the Gamburtsev Province and Dronning Maud Land, two of the major nucleation sites for the East Antarctic Ice Sheet (EAIS) were ~500 m higher 60 Ma ago. The increased elevation may have facilitated ephemeral ice cap development in the early Cenozoic. Between ca 25 and 50 Ma the northern Wilkes Subglacial Basin was ca 200 m higher than today and a major increase in regional elevation (>600 m) occurred over the last 20-15 Ma over the northern and southern Victoria Land in the Transantarctic Mountains (TAM). The most prominent signal is observed over the Ross Sea Rift (RSR) where predicted Neogene dynamic topography exceeds 1,000 m. The flow of warm mantle from the West Antarctic Rift System (WARS)may have driven these dynamic topography effects over the TAM and RSR. However, we found that these effects are comparatively less significant over the Marie Byrd Land Dome and the interior of the WARS. If these contrasting dynamic topography effects are included, then the predicted elevations of the Ross Sea Embayment ca 20 Ma ago are more similar to the interior of the WARS, with significant implications for the early development of the West Antarctic Ice Sheet

Large eddy simulations and direct numerical simulations of high speed turbulent reacting flows

This research is involved with the implementations of advanced computational schemes based on large eddy simulations (LES) and direct numerical simulations (DNS) to study the phenomenon of mixing and its coupling with chemical reactions in compressible turbulent flows. In the efforts related to LES, a research program was initiated to extend the present capabilities of this method for the treatment of chemically reacting flows, whereas in the DNS efforts, focus was on detailed investigations of the effects of compressibility, heat release, and nonequilibrium kinetics modeling in high speed reacting flows. The efforts to date were primarily focussed on simulations of simple flows, namely, homogeneous compressible flows and temporally developing hign speed mixing layers. A summary of the accomplishments is provided

Mixing and non-equilibrium chemical reaction in a compressible mixing layer

The effects of compressibility, chemical reaction exothermicity, and non-equilibrium chemical modeling in a reacting plane mixing layer were investigated by means of two dimensional direct numerical simulations. The chemical reaction was irreversible and second order of the type A + B yields Products + Heat. The general governing fluid equations of a compressible reacting flow field were solved by means of high order finite difference methods. Physical effects were then determined by examining the response of the mixing layer to variation of the relevant non-dimensionalized parameters. The simulations show that increased compressibility generally results in a suppressed mixing, and consequently a reduced chemical reaction conversion rate. Reaction heat release was found to enhance mixing at the initial stages of the layer growth, but had a stabilizing effect at later times. The increased stability manifested itself in the suppression or delay of the formation of large coherent structures within the flow. Calculations were performed for a constant rate chemical kinetics model and an Arrhenius type kinetic prototype. The choice of the model was shown to have an effect on the development of the flow. The Arrhenius model caused a greater temperature increase due to reaction than the constant kinetic model. This had the same effect as increasing the exothermicity of the reaction. Localized flame quenching was also observed when the Zeldovich number was relatively large

Large Eddy Simulations (LES) and Direct Numerical Simulations (DNS) for the computational analyses of high speed reacting flows

The principal objective is to extend the boundaries within which large eddy simulations (LES) and direct numerical simulations (DNS) can be applied in computational analyses of high speed reacting flows. A summary of work accomplished during the last six months is presented

Large eddy simulations and direct numerical simulations of high speed turbulent reacting flows

The main objective is to extend the boundaries within which large eddy simulations (LES) and direct numerical simulations (DNS) can be applied in computational analyses of high speed reacting flows. In the efforts related to LES, we were concerned with developing reliable subgrid closures for modeling of the fluctuation correlations of scalar quantities in reacting turbulent flows. In the work on DNS, we focused our attention to further investigation of the effects of exothermicity in compressible turbulent flows. In our previous work, in the first year of this research, we have considered only 'simple' flows. Currently, we are in the process of extending our analyses for the purpose of modeling more practical flows of current interest at LaRC. A summary of our accomplishments during the third six months of the research is presented

Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devices

Plasma nitriding was applied to ferritic stainless steel substrates to improve their performances as interconnects for solid oxide fuel cell devices. The samples underwent electrical conductivity test and SEM/EDS, TEM/EDS, environmental-SEM analyses. The first stages of corrosion were recorded in-situ with the e-SEM. Nitriding is effective in limiting the undesired chromium evaporation from the steel substrates and accelerates the corrosion kinetics, but its influence of the electrical conductivity is ambiguous. No intergranular corrosion is found in the steel substrate after long time operation. Nitriding helps commercially competitive porous coating to improve chromium retention properties of metal interconnects

Measurement of the Sintering Dynamics of polymeric powders at Near SLS Conditions

The sintering dynamics of materials used in the Selective Laser Sintering process impact greatly the thermal conditions of the powder bed. An experimental setup was developed to obtain sintering rate information at conditions very near to those of the SLS process. The system consists of a powder sample heated by a CO2 laser while maintained at constant thermal boundary conditions. The powder height is measured by means of an optical sensor, which avoids stress on the powder and allows fast data. acquisition. This paper discusses experiments conducted with this apparatus and further compares the obtained results with theoretical models and the previous work of others.Mechanical Engineerin